Deuteronomy 2:10
(The Emim formerly lived there, a people great and many, and tall as the Anakim.
Genesis 14:5
In the fourteenth year Chedorlaomer and the kings who were with him came and defeated the Rephaim in Ashteroth-karnaim, the Zuzim in Ham, the Emim in Shaveh-kiriathaim,
Numbers 13:22
They went up into the Negeb and came to Hebron. Ahiman, Sheshai, and Talmai, the descendants of Anak, were there. (Hebron was built seven years before Zoan in Egypt.)
Deuteronomy 2:11
Like the Anakim they are also counted as Rephaim, but the Moabites call them Emim.