Judges 13:21

But the angel of the LORD did no more appear to Manoah and to his wife. Then Manoah knew that he was an angel of the LORD.

Judges 6:22

And when Gideon perceived that he was an angel of the LORD, Gideon said, Alas, O Lord GOD! for I have seen an angel of the LORD face to face.

Judges 13:16

And the angel of the LORD said unto Manoah, Though you detain me, I will not eat of your food: and if you will offer a burnt offering, you must offer it unto the LORD. For Manoah knew not that he was an angel of the LORD.

Hosea 12:4-5

Yea, he had power over the angel, and prevailed: he wept, and made supplication unto him: he found him in Bethel, and there he spoke with us;

Treasury of Scripture Knowledge

Summary

But the angel of the LORD did no more appear to Manoah and to his wife. Then Manoah knew that he was an angel of the LORD.

Bible References

Knew

Judges 6:22
And when Gideon perceived that he was an angel of the LORD, Gideon said, Alas, O Lord GOD! for I have seen an angel of the LORD face to face.
Hosea 12:4
Yea, he had power over the angel, and prevailed: he wept, and made supplication unto him: he found him in Bethel, and there he spoke with us;